Sabtu, 07 Juni 2008

Rechargeable battery

Rechargeable battery

A rechargeable lithium polymer Nokia mobile phone battery.
A rechargeable lithium polymer Nokia mobile phone battery.
Further information: Rechargeable electricity storage system

A rechargeable battery, also known as a storage battery, is a group of two or more secondary cells. These batteries can be restored to full charge by the application of electrical energy. In other words, they are electrochemical cells in which the electrochemical reaction that releases energy is readily reversible. Rechargeable electrochemical cells are therefore a type of accumulator. They come in many different designs using different chemicals. Commonly used secondary cell chemistries are lead and sulfuric acid, nickel cadmium (NiCd), nickel metal hydride (NiMH), lithium ion (Li-ion), and lithium ion polymer (Li-ion polymer).

Rechargeable batteries can offer economic and environmental benefits when used instead of one-time-use disposable batteries. Most rechargeable battery technology has been adapted into the standard “AA”, “AAA”, “C”, “sub-C”, “D”, and “9-volt” (List of battery sizes) configurations that consumers are familiar with. While the rechargeable versions of these types of cells have a higher up-front cost than disposable batteries, rechargeable batteries can be discharged and recharged many times. Similarly, while the metals and chemicals in rechargeable cells can be more toxic than those in disposeable batteries, disposeable batteries nevertheless do release toxins into landfills and other more sensitive parts of the environment. Some manufacturers of NiMH type rechargeable batteries claim a lifespan up to 3000 charge cycles for their batteries.

Usage and applications

Unlike nonrechargeable batteries (primary cells), secondary cells must be charged before use. Attempting to recharge nonrechargeable batteries has a small chance of causing a battery explosion.

Some types of rechargeable batteries are susceptible to damage due to reverse charging if they are fully discharged; other types need to be fully discharged occasionally in order to maintain the capacity for deep discharge. Fully integrated battery chargers that optimize the charging current are available.

Rechargeable batteries currently are used for lower power applications such as automobile starters, portable consumer devices, tools, and uninterruptible power supplies. Emerging applications in hybrid vehicles and electric vehicles are driving the technology to improve cost, reduce weight, and increase lifetime. Future applications are proposed to use rechargeable batteries for load leveling, where they would store baseline electric power for use during peak load periods, and for renewable energy uses, such as storing power generated from photovoltaic arrays during the day to be used at night.

The National Electrical Manufacturers Association has estimated that U.S. demand for rechargeables is growing twice as fast as demand for nonrechargeables.[1]

Charging

Further information: Battery charger

During charging, the positive active material is oxidized, producing electrons, and the negative material is reduced, consuming electrons. These electrons constitute the current flow in the external circuit. The electrolyte may serve as a simple buffer for ion flow between the electrodes, as in lithium-ion and nickel-cadmium cells, or it may be an active participant in the electrochemical reaction, as in lead-acid cells.

The reactions in lead-acid cells are illustrated in the following diagrams.

Diagram of the charging of a secondary cell battery.
Diagram of the charging of a secondary cell battery.

Image:Lead-acid charging.svg Image:Lead-acid discharging.svg

The half-cell reactions and overall cell reaction for the lead-acid system are as follows:

Positive electrode

\mbox{PbO}_2 + \mbox{SO}_4^{2-} + 4\mbox{H}^+ +2e^- \begin{smallmatrix}{\mbox{discharge}}\\{\longrightarrow}\\{\longleftarrow}\\{\mbox{charge}}\end{smallmatrix} \mbox{PbSO}_4 + 2\mbox{H}_2\mbox{O}

Negative electrode

\mbox{Pb} + \mbox{SO}_4^{2-} \begin{smallmatrix}{\mbox{discharge}}\\{\longrightarrow}\\{\longleftarrow}\\{\mbox{charge}}\end{smallmatrix} \mbox{PbSO}_4 + 2e^-

Overall reaction

\mbox{PbO}_2 + \mbox{Pb} + 2\mbox{H}_2\mbox{SO}_4 \begin{smallmatrix}{\mbox{discharge}}\\{\longrightarrow}\\{\longleftarrow}\\{\mbox{charge}}\end{smallmatrix} 2\mbox{PbSO}_4 + 2\mbox{H}_2\mbox{O}

Battery charger
Battery charger

The energy used to charge rechargeable batteries mostly comes from household AC current/mains electricity using an adapter unit. It can be wired or wireless[citation needed]. Charging backup batteries using off-peak energy paid for by on-peak excess electric power from residential solar panels exactly matches the critical peak shortage and nightly electric surplus. This load-leveling function helps eliminate the need for expensive peaking power plants and helps amortize the cost of generators over more hours of operation. Charging from the 12-volt battery of a car is also possible. Human powered generators are commercially available. One can also use portable batteries to charge or to be used directly after recharging. Most battery chargers can take several hours to charge a battery (excepting Nano Titanate batteries). Most batteries can be charged in far less time than the most common simple battery chargers are capable of. Duracell and Rayovac now sell chargers that can charge AA- and AAA-size NiMH batteries in just 15 minutes; Energizer sells chargers that can additionally charge C/D-size and 9V NiMH batteries. Flow batteries don't need to be charged on place, because they can be charged by replacing the electrolyte liquid. Battery manufacturers' technical notes often refer to VPC. This is Volts Per Cell, and refers to the individual secondary cells that make up the battery. For example, to charge a 12 V battery (containing 6 cells of 2 V each) at 2.3 VPC requires a voltage of 15.6 V across the battery's terminals.

Recharging electric vehicles

Recharging an electric vehicle using off-peak energy paid for by on-peak excess electric power from residential solar panels exactly matches the critical peak shortage and nightly electric surplus. While electric vehicles can charge slowly at night, raising the nightly low electric use, solar panels can lower the daytime peak, flattening the daily usage curve and lowering the cost of electric power for all users.

Reverse charging

Reverse charging, which damages batteries, is when a rechargeable battery is recharged with its polarity reversed. Reverse charging can occur under a number of circumstances, the two most important being:

  • When a battery is incorrectly inserted into a charger.
  • When multiple batteries are used in series in a device. When one battery completely discharges ahead of the rest, the other batteries in series may force the discharged battery to discharge to below zero voltage.

Active components

The active components in a secondary cell are the chemicals that make up the positive and negative active materials, and the electrolyte. The positive and negative are made up of different materials, with the positive exhibiting a reduction potential and the negative having an oxidation potential. The sum of these potentials is the standard cell potential or voltage.

In primary cells the positive and negative electrodes are known as the cathode and anode, respectively. Although this convention is sometimes carried through to rechargeable systems—especially with lithium-ion cells, because of their origins in primary lithium cells—this practice can lead to confusion. In rechargeable cells the positive electrode is the cathode on discharge and the anode on charge, and vice versa for the negative electrode.

Example: Nickel Metal Hydride

Nickel oxyhydroxide (NiOOH) is the active component in the positive, while the negative is composed of hydrogen in the form of metal hydride. The electrolyte of this secondary cell is an aqueous form of potassium hydroxide.

In the discharge process, the nickel oxyhydroxide is reduced to nickel hydroxide and the metal hydride is oxidized to an alloy.

Nickel-Metal Hydride

Location Reactions Voltage
Negative MH + OH- → M + H2O + e- 0.83
Positive NiOOH + H2O + e- → Ni(OH)2 + OH- 0.52
Overall NiOOH + MH → Ni(OH)2 + M 1.35

Table of rechargeable battery technologies

Type Voltagea Energy densityb Powerc Effi.d E/$e Disch.f Cyclesg Lifeh
(V) (MJ/kg) (Wh/kg) (Wh/L) (W/kg) (%) (Wh/$) (%/mo) (#) (years)
Lead-acid 2.1 0.11-0.14 30-40 60-75 180 70%-92% 5-8 3%-4% 500-800 3 (car battery), 20 (stationary)
VRLAi 2.105







Ni-iron 1.2 0.18 50
100 65% 5-7.3[2] 20%-40%

Ni-cadmium 1.2 0.14-0.22 40-60 50-150 150 70%-90%
20% 1500
NiMH 1.2 0.11-0.29 30-80 140-300 250-1000 66% 1.37[1] 20% 1000
Ni-zinc 1.7 0.22 60 170

2-3.3


Li ion 3.6 0.58 160 270 1800 99.9% 2.8-5[3] 5%-10% 1200 2-3
Li polymer 3.7 0.47-0.72 130-200 300 3000+ 99.8% 2.8-5.0

~0.5
LiFePO4 3.25
80-120 170 [4] 1400
0.7-1.6
2000+[5]
Li sulfur[6] 2.0
400[7]






Nano Titanate[8] 2.3
90
4000+ 87-95%r 0.5-1.0[9]
9000+ 20+
Thin film Li ?

350 959 6000 ?p[10]
40000
ZnBr









V redox 1.4-1.6
25-35[11]






NaS




89%-92%



Molten salt

70-110[12]
150-220
4.54[13]
3000+ 8+
Super iron









Silver zinc

130 240





Alkaline 1.5







Notes

For brevity, entries in the table had to be abbreviated. For a full description, please refer to the individual article about each type. Battery types for which there is no article yet are listed below.

Graph of mass energy densities of several secondary cells
Graph of mass energy densities of several secondary cells
  • b Energy density = energy/weight or energy/size, given in three different units
  • c Specific power = power/weight in W/kg
  • d Charge/discharge efficiency in %
  • e Energy/consumer price in W·h/US$ (approximately)
  • j Safe Depth of Discharge to maintain lifecycles
  • f Self-discharge rate in %/month
  • g Cycle durability in number of cycles
  • h Time durability in years
  • i VRLA or recombinant includes gel batteries and absorbed glass mats
  • k most prominent example for an application
  • l "heavy" and "light" refer to low and high energy density, respectively. Of course, some batteries with high energy density can be quite heavy.
  • p Pilot production
  • q Can't be stored in discharged condition
  • r Depending upon charge rate
  • t temperature related problems
  • x charge problems: If the battery discharges below a certain voltage it may never be able to hold a charge again, also if overcharged the battery becomes extremely unstable and may explode.
  • y More than 97 percent of all battery lead is recycled http://www.batterycouncil.org/recycling.html
  • z These batteries can be recharged nearly instantaneously by replacing the electrolyte.

Common Rechargeable Battery Types

Nickel Cadmium Battery (NiCd)

Created by Waldemar Jungner of Sweden in 1899 which was based on Thomas Edison's first alkaline battery. Using nickel oxide hydroxide and metallic cadmium as electrodes, NiCd batteries have longer life cycles and hold electrical charge longer. However, their voltage potential difference are often less than that of Nickel-metal Hydride's.

Nickel-Metal Hydride Battery (NiMH)

First developed around 1980's. The battery has a hydrogen-absorbing alloy for the negative electrode instead of cadmium. Even though NiMH batteries have higher voltage outputs, the batteries discharge quicker and have a limited service life compared to NiCd.

Lithium-ion Battery

The technology behind Lithium-ion battery has not yet fully reached maturity. However, the batteries are the type of choice in many consumer electronics and have one of the best energy-to-mass ratios, no memory effect, and a slow loss of charge when not in use. The popularity of Lithium-ion has spread as their technology continues to improve.

Less common types

Lithium sulfur battery
A new battery chemistry developed by Sion Power[14] since 1994. Claims superior energy to weight than current lithium technologies on the market. Also lower material cost may help this product reach the mass market.[15] Not to be confused with lithium sulfur dioxide (Li-SO2) batteries which explode when recharged.
Thin film lithium battery
An emerging refinement of the lithium ion technology by Excellatron.[16] The developers claim a very large increase in recharge cycles, around 40,000 cycles. Higher charge and discharge rates. At least 5C charge rate. Sustained 60C discharge, and 1000C peak discharge rate. And also a significant increase in specific energy, and energy density.[17]
Smart battery
A smart battery has the voltage monitoring circuit built inside. See also Smart battery system.
Carbon foam-based lead acid battery
Firefly Energy has developed a carbon foam-based lead acid battery with a reported energy density of 30-40% more than their original 38 W·h/kg[18], with long life and very high power density.

Recent developments

In 2007, assistant professor Yi Cui and colleagues at Stanford University's Department of Materials Science and Engineering discovered that using silicon nanowires gave rechargeable lithium ion batteries 10 times more charge.[19][20]

( Thanks to Wikipedia : By BSa)

Battery charger (English)

Battery charger


This unit charges the batteries until they reach a specific voltage and then it trickle charges the batteries until it is disconnected.
This unit charges the batteries until they reach a specific voltage and then it trickle charges the batteries until it is disconnected.
A simple charger equivalent to a AC-DC wall adapter. It applies 300mA to the battery at all times, which will damage the battery if left connected too long.
A simple charger equivalent to a AC-DC wall adapter. It applies 300mA to the battery at all times, which will damage the battery if left connected too long.

A battery charger is a device used to put energy into a cell or (rechargeable) battery by forcing an electric current through it.

The charge current depends upon the technology and capacity of the battery being charged. For example, the current that should be applied to recharge a 12 V car battery will be very different from the current for a mobile phone battery.

Types of battery chargers

Simple

A simple charger works by connecting a constant DC power source to the battery being charged. The simple charger does not alter its output based on time or the charge on the battery. This simplicity means that a simple charger is inexpensive, but there is a tradeoff in quality. Typically, a simple charger takes longer to charge a battery to prevent severe over-charging. Even so, a battery left in a simple charger for too long will be weakened or destroyed due to over-charging.

Trickle

Main article: trickle charging

A trickle charger is a kind of simple charger that charges the battery slowly, at the self-discharge rate. A trickle charger is the slowest kind of battery charger. A battery can be left in a trickle charger indefinitely. Leaving a battery in a trickle charger keeps the battery "topped up" but never over-charges.

Timer-based

The output of a timer charger is terminated after a pre-determined time. Timer chargers were the most common type for high-capacity Ni-Cd cells in the late 1990s for example (low-capacity consumer Ni-Cd cells were typically charged with a simple charger).

Often a timer charger and set of batteries could be bought as a bundle and the charger time was set to suit those batteries. If batteries of lower capacity were charged then they would be overcharged, and if batteries of higher capacity were charged they would be only partly charged. With the trend for battery technology to increase capacity year on year, an old timer charger would only partly charge the newer batteries.

Timer based chargers also had the drawback that charging batteries that were not fully discharged, even if those batteries were of the correct capacity for the particular timed charger, would result in over-charging.

Intelligent

Output current depends upon the battery's state. An intelligent charger may monitor the battery's voltage, temperature and/or time under charge to determine the optimum charge current at that instant. Charging is terminated when a combination of the voltage, temperature and/or time indicates that the battery is fully charged.

For Ni-Cd and NiMH batteries, the voltage across the battery increases slowly during the charging process, until the battery is fully charged. After that, the voltage decreases, which indicates to an intelligent charger that the battery is fully charged. Such chargers are often labeled as a ΔV, or "delta-V," charger, indicating that they monitor the voltage change.

A typical intelligent charger fast-charges a battery up to about 85% of its maximum capacity in less than an hour, then switches to trickle charging, which takes several hours to top off the battery to its full capacity. [1]

Fast

Fast chargers make use of control circuitry in the batteries being charged to rapidly charge the batteries without damaging the cells' elements. Most such chargers have a cooling fan to help keep the temperature of the cells under control. Most are also capable of acting as a standard overnight charger if used with standard NiMH cells that do not have the special control circuitry. Some fast chargers, such as those made by Energizer, can fast-charge any NiMH battery even if it does not have the control circuit.

Pulse

Some chargers use pulse technology in which a pulse is fed to the battery. This DC pulse has a strictly controlled rise time, shape, pulse width, pulse repetition rate (frequency) and amplitude. This technology is said to work with any size, voltage, capacity or chemistry of batteries, including automotive and valve-regulated batteries. [2] [3] .

Several kinds of pulse charging are patented [4] [5] [6] .

Some chargers use pulses to check the current battery state when the charger is first connected, then use constant current charging during fast charging, then use pulse charging as a kind of trickle charging to maintain the charge. [7]

Some chargers use "negative pulse charging", also called "reflex charging" or "burp charging" [8] . Such chargers use both positive and brief negative current pulses. Such chargers don't work any better than pulse chargers that only use positive pulses [9] [10] .

Inductive

Main article: Inductive charging

Inductive battery chargers use electromagnetic induction to charge batteries. A charging station sends electromagnetic energy through inductive coupling to an electrical device, which stores the energy in the batteries. This is achieved without the need for metal contacts between the charger and the battery. It is commonly used in electric toothbrushes, and other devices used in bathrooms, because there is no risk of electrocution.

USB-based

Pay-per-charge kiosk, illustrating the variety of mobile phone charger connectors.
Pay-per-charge kiosk, illustrating the variety of mobile phone charger connectors.

Since the Universal Serial Bus specification provides for a five-volt power supply, it's possible to use a USB cable as a power source for recharging batteries. Products based on this approach include chargers designed to charge standard NiMH cells[11], and custom NiMH batteries with built-in USB plugs and circuitry which eliminate the need for a separate charger.[12] Moixa Energy patented a design of batteries, branded USBCELL, that incorporate their own USB chargers internally, complete with their own plugs. In the currently available AA battery design, the positive end of the battery doubles as a flip-cap for the built-in USB plug.[13]


Charge rate

This is often denoted as C and signifies a charge or discharge rate equal to the capacity of a battery divided by 1 hour. For example C for a 1600 mAh battery would be 1600 mA (or 1.6 amps). 2C is twice this rate and 1/2C is half the rate.

Applications

Since a battery charger is intended to be connected to a battery, it may not have voltage regulation or filtering of the DC voltage output. Battery chargers equipped with both voltage regulation and filtering may be identified as battery eliminators.


Mobile phone charger

Most mobile phone chargers are not really chargers, only adapters that provide a power source for the charging circuitry which is almost always contained within the mobile phone.[14] Mobile phones can usually accept relatively wide range of voltages, as long as it is sufficiently above the phone battery's voltage. However, if the voltage is too high, it can damage the phone. Mostly, the voltage is 5 volts or slightly higher, but it can sometimes vary up to 12 volts when the power source is not loaded.

Battery chargers for mobile phones and other devices are notable in that they come in a wide variety of DC connector-styles and voltages, most of which are not compatible with other manufactuers' phones or even different models of phones from a single manufacturer.

Users of publicly accessible charging kiosks must be able to cross-reference connectors with device brands/models and individual charge parameters and thus ensure delivery of the correct charge for their mobile device. A database-driven system is one solution, and is being incorporated into some of the latest designs of charging kiosks.

The Ionhub charger  can simultaneously charge several electronic devices: iPod Nano, Razr, Nintendo DS Lite, BlackBerry, portable DVD player, and electric shaver.
The Ionhub charger [15] can simultaneously charge several electronic devices: iPod Nano, Razr, Nintendo DS Lite, BlackBerry, portable DVD player, and electric shaver.

There are also human-powered chargers sold on the market, which typically consists of a dynamo powered by a hand crank and extension cords. There are also solar chargers.[16]

China and other countries are making a national standard on mobile phone chargers using the USB standard.[17]

Battery charger for vehicles

There are two main types of charges for vehicles:

  • To recharge a fuel vehicle's starter battery, where a modular charger is used.
  • To recharge an electric vehicle (EV) battery pack.

Battery electric vehicle

These vehicles include a battery pack, so generally use series charger.

A 10 Ampere-hour battery could take 15 hours to get fully charged from a fully discharged condition with a 1 Ampere charger as it would require roughly 1.5 times the battery's capacity.

Public EV charging [18] heads (aka: stations) provide 6kW (host power of 208 to 240 VAC off a 40 amp circuit). 6kW will recharge an EV 6 times faster than 1kW overnight charging.

Rapid charging gives even faster recharge times and are only limited by available AC power and the type of charging system [19].

On board EV chargers (change AC power to DC power to recharge the EV's pack) can be:

  • Isolated: they make no connection between the A/C electrical mains and the batteries being charged. Isolated chargers can be put in parallel using more than one power source to boost charge current and reduce recharging time.
  • Non-isolated: the battery pack has a connection the A/C outlet's wiring. Un-isolated chargers can not be using in parallel, and should be disconnected from each other even with the AC power off.

Power Factor Correction (PFC) chargers can more closely approach the maximum current the plug can deliver, shortening charging time.

Some battery electric vehicle charging devices includes:

  • Manzanita Micro Power factor correction (PFC) PFC series chargers (mid price range) (non-isolated) (90 to 240 VAC input, 12 to 366 VDC output).
  • Russco [20] SC and DSO series chargers (low price range) (non-isolated) (120 VAC input, 72 to 120 VDC battery packs, 120 to 156 VDC pack require their AC input boost transformer).
  • Zivan [21] NG series chargers (mid price range) (isolated).
  • BRUSA Elektronik AG (high price range) (isolated).

Charge stations

A listing of public EV charging in the U.S.A.[22]

Project Better Place is going to deploy a network of charge stations. It also subsidize vehicle battery costs through leases and credits.

Prolonging battery life

Many rumors circulate about the best practices to prolong battery life. What practices are best depend on the type of battery. It is rumored that Nickel-based cells, such as NiMH and NiCd, need to be fully discharged before each charge, or else the battery loses capacity over time in a phenomenon known as memory effect. However, this is only partially accurate: nickel alloy cells can be charged at any point throughout their discharge cycle--they do not have to be fully discharged. Memory effect should instead be prevented by fully discharging the battery once a month (once every 30 charges)[23]. This extends the life of the battery since memory effect is prevented while avoiding full charge cycles which are known to be hard on all types of dry-cell batteries, eventually resulting in a permanent decrease in battery capacity.

Most modern cell phones, laptops, and most electric vehicles use Lithium-ion batteries. Contrary to some recommendations, these batteries actually last longest if the battery is not fully charged; fully charging and discharging them will degrade their capacity relatively quickly. Degradation occurs faster at higher temperatures. Lithium batteries degrade more while fully charged than if it is only 40% charged. The conditions of high temperature combined with full charge are exactly the scenario occurring when a laptop computer is run on AC power. Degradation in lithium-ion batteries is caused by an increased internal battery resistance due to cell oxidation. This decreases the efficiency of the battery, resulting in less net current available to be drawn from the battery.

Internal combustion engine vehicles, such as boats, RVs, ATVs, motorcycles, cars, trucks, and more use lead acid batteries. These batteries employ a sulfuric acid electrolyte and can generally be charged and discharged without exhibiting memory effect, though sulfation (a chemical reaction in the battery which deposits a layer of sulfates on the lead) will occur over time. Keeping the electrolyte level in the recommended range is necessary. When discharged, these batteries should be recharged immediately in order to prevent sulfation. These sulfates are electrically insulating and therefore interfere with the transfer of charge from the sulfuric acid to the lead, resulting in a lower maximum current than can be drawn from the battery. Sulfated lead acid batteries typically need replacing. Good ventilation and avoidance of ignition sources (e.g., sparks) is wise when recharging, since charging a lead acid battery generates highly explosive hydrogen gas.

( Thanks to Wikipedia ; By BSa Maxima)

Battery (English)

Battery (electricity)

JVarious batteries (clockwise from bottom left): two 9-volt, two AA, triple AAA, one D, a handheld ham radio battery, a cordless phone battery, a camcorder battery, and one C.
Various batteries (clockwise from bottom left): two 9-volt, two AA, triple AAA, one D, a handheld ham radio battery, a cordless phone battery, a camcorder battery, and one C.

In electronics, a battery is two or more electrochemical cells[1] which store chemical energy and make it available as electrical energy. Common usage has evolved to include a single electrical cell in the definition.[2] There are many types of electrochemical cells, including galvanic cells, electrolytic cells, fuel cells, flow cells and voltaic piles.[3] A battery's characteristics may vary due to many factors including internal chemistry, current drain and temperature.

One common division of batteries distinguishes two types: primary (disposable) and secondary (rechargeable). Primary batteries are designed to be used once only because they use up their chemicals in an effectively irreversible reaction. Secondary batteries can be recharged because the chemical reactions they use are reversible; they are recharged by running a charging current through the battery, but in an opposite direction to the discharge current.[4] Secondary, also called rechargeable batteries can be charged and discharged many times before wearing out. After wearing out some batteries can be recycled.[5]

Although an early form of battery may have been used in antiquity, the modern development of batteries started with the Voltaic pile, invented by the Italian physicist Alessandro Volta in 1800. Since then, batteries have gained popularity as they became portable and useful for many purposes.[6] The widespread use of batteries has created many environmental concerns, such as toxic metal pollution.[7] Many reclamation companies recycle batteries to reduce the number of batteries going into landfills.[8]

History

The modern story of the battery begins in the 1780s with the discovery of "animal electricity" by Luigi Galvani, which he published in 1791.[9] He created an electric circuit consisting of two different metals, with one touching a frog's leg and the other touching both the leg and the first metal, thus closing the circuit. In modern terms, the frog's leg served as both electrolyte and detector, and the metals served as electrodes. He noticed that even though the frog was dead, its legs would twitch when he touched them with the metals.

Volta realized that the frog's moist tissues could be replaced by cardboard soaked in salt water, and the frog's muscular response could be replaced by another form of electrical detection. He already had studied the electrostatic phenomenon of capacitance, which required measurements of electric charge and of electrical potential. Building on this experience Volta was able to detect electric current flow through his system, now called a voltaic cell, or cell for short. The terminal voltage of a cell that is not discharging is called its electromotive force (emf), and has the same unit as electrical potential, named (voltage) and measured in volts, in honor of Volta. In 1799, Volta invented the battery by placing many voltaic cells in series, literally piling them one above the other. This Voltaic Pile gave a greatly enhanced net emf for the combination,[10] with a voltage of about 50 volts for a 32-cell pile.[11] In many parts of Europe batteries continue to be called piles.

Unfortunately, Volta did not appreciate that the voltage was due to chemical reactions. He thought that his cells were an inexhaustible source of energy, and that the associated chemical effects (e.g. corrosion) were a mere nuisance, rather than, as Michael Faraday showed around 1830, an unavoidable consequence of their operation.

While early batteries were of great value for experimental purposes, their limitations made them impractical for a large current drain. Later, starting with the Daniell cell in 1836, batteries provided more reliable currents and were adopted by industry for use in stationary devices, particularly in telegraph networks where they were the only practical source of electricity, since electrical distribution networks did not exist then.[12] These wet cells used liquid electrolytes, which were prone to leakage and spillage if not handled correctly. Many used glass jars to hold their components, which made them fragile. These characteristics made wet cells unsuitable for portable appliances. Near the end of the 19th century, the invention of Dry cell batteries, which replaced liquid electrolyte with a paste, made portable electrical devices practical.

The battery has since become a common power source for many household and industrial applications. According to a 2005 estimate, the worldwide battery industry generates US$48 billion in sales annually.[13]

How batteries work

Main article: Electrochemical cell
A voltaic cell for demonstration purposes. In this example the two half-cells are linked by a salt bridge separator that permits the transfer of ions, but not water molecules.
A voltaic cell for demonstration purposes. In this example the two half-cells are linked by a salt bridge separator that permits the transfer of ions, but not water molecules.

A battery is a device that converts chemical energy directly to electrical energy.[14] It consists of one or more voltaic cells. Each voltaic cell consists of two half cells connected in series by a conductive electrolyte. One half-cell is the positive electrode and the other is the negative electrode. The electrodes do not touch each other but are electrically connected by the electrolyte, which can be either solid or liquid.[15] In many cells, the materials are enclosed in a container, and a separator, which is porous to the electrolyte, which prevents the electrodes from coming into contact.

Each half cell has an electromotive force (or emf), determined by its ability to drive electric current from the interior to the exterior of the cell. The net emf of the battery is the difference between the emfs of its half-cells, as first recognized by Volta.[16] Thus, if the electrodes have emfs \mathcal{E}_1 and \mathcal{E}_2, then the net emf is \mathcal{E}_{2}-\mathcal{E}_{1}. (Hence, two identical electrodes and a common electrolyte give a zero net emf.)

The electrical potential difference, or \displaystyle{\Delta V_{bat}} across the terminals of a battery is known as terminal voltage and is measured in volts.[17] The terminal voltage of a battery that is neither charging nor discharging is called the open-circuit voltage and equals the emf of the battery. Because of internal resistance[18], the terminal voltage of a battery that is discharging is smaller in magnitude than the open-circuit voltage and the terminal voltage of a battery that is charging exceeds the open-circuit voltage.[19] An ideal battery has negligible internal resistance, so it would always have a terminal voltage of \mathcal{E}. This means that to produce a potential difference of 1.5 V, chemical reactions inside would perform 1.5 J of work for a charge of 1 C.[17]

The voltage developed across a cell's terminals depends on the chemicals used in it and their respective concentrations. For example, alkaline and carbon-zinc cells both measure approximately 1.5 volts, due to the energy release of the associated chemical reactions.[20] Because of the high electrochemical potential changes in the reactions of lithium compounds, lithium cells can provide as much as 3 volts or more.[21]

Classification of batteries

Disposable and rechargeable

From top to bottom: Two button cells, a 9-volt PP3 battery, an AAA battery, an AA battery, a C battery, a D battery, a large 3R12.
From top to bottom: Two button cells, a 9-volt PP3 battery, an AAA battery, an AA battery, a C battery, a D battery, a large 3R12.

Batteries are usually divided into two broad classes:

  • Primary batteries irreversibly (within limits of practicality) transform chemical energy to electrical energy. When the initial supply of reactants is exhausted, energy cannot be readily restored to the battery by electrical means.[22]
  • Secondary batteries can be recharged; that is, they can have their chemical reactions reversed by supplying electrical energy to the cell, restoring their original composition.[23]

Historically, some types of primary batteries used, for example, for telegraph circuits, were restored to operation by replacing the components of the battery consumed by the chemical reaction. Secondary batteries are not indefinitely rechargeable due to dissipation of the active materials, loss of electrolyte and internal corrosion.

From a user's viewpoint, at least, batteries can be generally divided into two main types: non-rechargeable (disposable) and rechargeable. Each type is in wide usage, as each has its own advantages and disadvantages.[24]

Disposable batteries, also called primary cells, are intended to be used once and discarded. These are most commonly used in portable devices with either low current drain, are only used intermittently, or are used well away from an alternative power source. Primary cells were also commonly used for alarm and communication circuits where other electric power was only intermittently available. Primary cells cannot be reliably recharged, since the chemical reactions are not easily reversible and active materials may not return to their original forms. Battery manufacturers recommend against attempting to recharge primary cells, although some electronics enthusiasts claim it is possible to do so using special types of chargers.[25]

By contrast, rechargeable batteries or secondary cells can be recharged by applying electrical current, which reverses the chemical reactions that occur during its use. Devices to supply the appropriate current are called chargers or rechargers.

The oldest form of rechargeable battery still in modern usage is the "wet cell" lead-acid battery.[26] This battery is notable in that it contains a liquid in an unsealed container, requiring that the battery be kept upright and the area be well ventilated to ensure safe dispersal of the hydrogen gas produced by these batteries during overcharging. The lead-acid battery is also very heavy for the amount of electrical energy it can supply. Despite this, its low manufacturing cost and its high surge current levels make its use common where a large capacity (over approximately 10Ah) is required or where the weight and ease of handling are not concerns.

A common form of lead-acid battery is the modern wet-cell car battery. This can deliver approximately 10,000 watts of power over a short period and has a peak current output that varies from 450 to 1100 amperes. An improved type of liquid electrolyte battery is the sealed valve regulated lead acid (VRLA) battery, popular in the automotive industry as a replacement for the lead-acid wet cell, as well as in many lower capacity roles including smaller vehicles and stationary applications such as emergency lighting and alarm systems. The one-way pressure activated valve eliminates electrolyte evaporation while allowing out-gassing to prevent rupture. This greatly improves resistance to damage from vibration and heat. VRLA batteries have the electrolyte immobilized, usually by one of two means:

  • Gel batteries (or "gel cell") contain a semi-solid electrolyte to prevent spillage.
  • Absorbed Glass Mat (AGM) batteries absorb the electrolyte in a special fiberglass matting

Other portable rechargeable batteries include several "dry cell" types, which are sealed units and are therefore useful in appliances such as mobile phones and laptop computers. Cells of this type (in order of increasing power density and cost) include nickel-cadmium (NiCd), nickel metal hydride (NiMH) and lithium-ion (Li-Ion) cells.

Recent developments include batteries with embedded functionality such as USBCELL, with a built-in charger and USB connector within the AA format, enabling the battery to be charged by plugging into a USB port without a charger,[27] and low self-discharge (LSD) mix chemistries such as Hybrio,[28] ReCyko,[29] and Eneloop,[30] where cells are precharged prior to shipping.

Disposable

Not designed to be rechargeable - sometimes called "primary cells". "Disposable" may also imply that special disposal procedures must take place for proper disposal according to regulation, depending on battery type.

  • Zinc-carbon battery: mid cost, used in light drain applications.
  • Zinc-chloride battery: similar to zinc-carbon but slightly longer life.
  • Alkaline battery: alkaline/manganese "long life" batteries widely used in both light-drain and heavy-drain applications.
  • Silver-oxide battery: commonly used in hearing aids, watches, and calculators.
  • Lithium-Thionyl Chloride battery: used in industrial applications, including computers, electric meters and other devices which contain volatile memory circuits and act as a "carryover" voltage to maintain the memory in the event of a main power failure. Other applications include providing power for wireless gas and water meters. The cells are rated at 3.6 Volts and come in 1/2AA, AA, 2/3A, A, C, D & DD sizes. They are relatively expensive, but have a long shelf life, losing less than 10% of their capacity in ten years.[31]
  • Mercury battery: formerly used in digital watches, radio communications, and portable electronic instruments. Manufactured only for specialist applications due to toxicity.
  • Zinc-air battery: commonly used in hearing aids.
  • Thermal battery: high-temperature reserve. Almost exclusively military applications.
  • Water-activated battery: used for radiosondes and emergency applications.
  • Nickel Oxyhydroxide battery: Ideal for applications that use bursts of high current, such as digital cameras. They will last two times longer than alkaline batteries in digital cameras.[32]
  • Paper battery: In August 2007, a research team at RPI (led by Drs. Robert Linhardt, Pulickel M. Ajayan, and Omkaram Nalamasu) developed a paper battery with aligned carbon nanotubes, designed to function as both a lithium-ion battery and a supercapacitor, using ionic liquid, essentially a liquid salt, as electrolyte. The sheets can be rolled, twisted, folded, or cut into numerous shapes with no loss of integrity or efficiency, or stacked, like printer paper (or a voltaic pile), to boost total output. As well, they can be made in a variety of sizes, from postage stamp to broadsheet. Their light weight and low cost make them attractive for portable electronics, aircraft, and automobiles, while their ability to use electrolytes in blood make them potentially useful for medical devices such as pacemakers. In addition, they are biodegradable, unlike most other disposable cells.[33][34]

Rechargeable

A rechargeable lithium polymer Nokia mobile phone battery.
A rechargeable lithium polymer Nokia mobile phone battery.

Also known as secondary batteries or accumulators. The National Electrical Manufacturers Association has estimated that U.S. demand for rechargeables is growing twice as fast as demand for non-rechargeables. [35] There are a few main types:

  • Nickel-cadmium battery (NiCd): Best used for motorized equipment and other high-discharge, short-term devices. NiCd batteries can withstand even more drain than NiMH; however, the mAh rating is not high enough to keep a device running for very long, and the memory effect is far more severe.[36]
  • Nickel-metal hydride battery (NiMH): Best used for high-tech devices. NiMH batteries can last up to four times longer than alkaline batteries because NiMH can withstand high current for a long while.[37]
  • Lithium ion battery: commonly used in digital cameras. Sometimes used in watches and computer clocks. Very long life (up to ten years in wristwatches) and capable of delivering high currents but expensive. Will operate in sub-zero temperatures.
  • Rechargeable alkaline battery: Uses similar chemistry as non-rechargeable alkaline batteries and are best suited for similar applications. [38] Additionally, they hold their charge for years, unlike NiCd and NiMH batteries. However drain/charging pattern can greatly affect their efficacy and lifespan.
  • LiFeP as used in the OLPC laptop.

Flow batteries

Flow batteries are a special class of rechargeable battery where additional quantities of electrolyte are stored outside the main power cell of the battery, and circulated through it by pumps or by movement.[39] Flow batteries can have extremely large capacities and are used in marine applications and are gaining popularity in grid energy storage applications.

Zinc-bromine[39] and vanadium redox batteries are typical examples of commercially available flow batteries.

Homemade cells

Almost any liquid or moist object that has enough ions to be electrically conductive can serve as the electrolyte for a cell. As a novelty or science demonstration, it is possible to insert two electrodes made of different metals into a lemon,[40] potato,[41] et cetera and generate small amounts of electricity. "Two-potato clocks" are also widely available in hobby and toy stores; they consist of a pair of cells, each consisting of a potato (lemon, et cetera) with two electrodes inserted into it, wired in series to form a battery with enough voltage to power a digital clock.[42] Homemade cells of this kind are of no real practical use, because they produce far less current—and cost far more per unit of energy generated—than commercial cells, due to the need for frequent replacement of the fruit or vegetable. In addition, one can make a voltaic pile from two coins (such as a nickel and a penny) and a piece of paper towel dipped in salt water. Such a pile would make very little voltage itself, but when many of them are stacked together in series, they can replace normal batteries for a short amount of time.[43]

Sony has developed a biologically friendly battery that generates electricity from sugar in a way that is similar to the processes observed in living organisms. The battery generates electricity through the use of enzymes that break down carbohydrates, which are essentially sugar.[44]

Lead acid cells can easily be manufactured at home, but a tedious charge/discharge cycle is needed to 'form' the plates. This is a process whereby lead sulfate forms on the plates, and during charge is converted to lead dioxide (positive plate) and pure lead (negative plate). Repeating this process results in a microscopically rough surface, with far greater surface area being exposed. This increases the current the cell can deliver. For an example, see [3].

Daniell cells are also easy to make at home. Aluminum-air batteries can also be produced with high purity aluminum. Aluminum foil batteries will produce some electricity, but they are not very efficient, in part because a significant amount of hydrogen gas is produced.

Battery packs

The cells in a battery can be connected in parallel, series or in both. A parallel combination of cells has the same voltage as a single cell, but can supply a higher current (the sum of the currents from all the cells). A series combination has the same current rating as a single cell but its voltage is the sum of the voltages of all the cells. Most practical electrochemical batteries, such as 9-volt flashlight batteries and 12-volt automobile batteries, have several cells connected in series inside the casing.[45] Parallel arrangements suffer from the problem that, if one cell discharges faster than its neighbour, current will flow from the full cell to the empty cell, wasting power and possibly causing overheating. Even worse, if one cell becomes short-circuited due to an internal fault, its neighbour will be forced to discharge its maximum current into the faulty cell, leading to overheating and possibly explosion.[46] Cells in parallel are therefore usually fitted with an electronic circuit to protect them against these problems. In both series and parallel types, the energy stored in the battery is equal to the sum of the energies stored in all the cells.

Traction batteries

Traction batteries are high-power batteries designed to provide propulsion to move a vehicle, such as an electric car or tow motor. A major design consideration is power to weight ratio since the vehicle must carry the battery.[47] While conventional lead acid batteries[48] with liquid electrolyte have been used, gelled electrolyte[49] and AGM-type[50] can also be used, especially in smaller sizes.

The largest installations of batteries for propulsion of vehicles are found in submarines, although the toxic gas produced by seawater contact with acid electrolyte is a considerable hazard.

Battery types commercially used in electric vehicles include

See also: battery electric vehicles and hydrogen vehicle.

Battery capacity and discharging

A device to check the charge of batteries
A device to check the charge of batteries

The more electrolyte and electrode material there is in the cell, the greater the capacity of the cell. Thus a small cell has less capacity than a larger cell, given the same chemistry (e.g. alkaline cells), though they develop the same open-circuit voltage.[51]

Because of the chemical reactions within the cells, the capacity of a battery depends on the discharge conditions such as the magnitude of the current, the duration of the current, the allowable terminal voltage of the battery, temperature and other factors.[51]

The available capacity of a battery depends upon the rate at which it is discharged.[52] If a battery is discharged at a relatively high rate, the available capacity will be lower than expected.

The battery capacity that battery manufacturers print on a battery is the product of 20 hours multiplied by the maximum constant current that a new battery can supply for 20 hours at 68 F° (20 C°),[53] down to a predetermined terminal voltage per cell.

A battery rated at 100 A·h will deliver 5 A over a 20 hour period at room temperature. However, if it is instead discharged at 50 A, it will run out of charge before the theoretically-expected 2 hours.

For this reason, a battery capacity rating is always related to an expected discharge duration—the standard duration is 20 hours.

t = \frac Q I

where

Q is the battery capacity (typically given in mA·h).
I is the current drawn from battery (mA).
t is the amount of time (in hours) that a battery can sustain.

The relationship between current, discharge time, and capacity for a lead acid battery is expressed by Peukert's law. The efficiency of a battery is different at different discharge rates. When discharging at low rate, the battery's energy is delivered more efficiently than at higher discharge rates.

In general, the higher the ampere-hour rating, the longer the battery will last for a certain load. Installing batteries with different A·h ratings will not affect the operation of a device rated for a specific voltage unless the load limits of the battery are exceeded. Theoretically, a battery would operate at its A·h rating, but realistically, high-drain loads like digital cameras can result in lower actual energy, most notably for alkaline batteries.[24] For example, a battery rated at 2000 mA·h may not sustain a current of 1 A for the full two hours.

Typical alkaline battery sizes and capacities[54] (at lowest discharge rates)
Diagram ↓ Size ↓ Capacity (mA·h) ↓ Voltage ↓ ANSI/NEDA ↓ IEC ↓ Diam. (mm) ↓ Mass (g) ↓ Height (mm) ↓ Length (mm) ↓ Width (mm) ↓

AAAA 625 1.5 25A LR8D425 8.3 6.5 42.5 cylindrical cylindrical
Image:N battery size.svg N 1000 1.5 910A LR1 12 9 30.2 cylindrical cylindrical
Image:AAA battery size.svg AAA 1250 1.5 24A LR03 10.5 11.5 44.5 cylindrical cylindrical
Image:AA battery size.svg AA 2850 1.5 15A LR6 14.5 23 50.5 cylindrical cylindrical

J 625 6 1412A 4LR61 prismatic 30 48.5 35.6 9.18

9V 625 9 1604A 6LR61 prismatic 45.6 48.5 26.5 17.5
Image:C battery size.svg C 8350 1.5 14A LR14 26.2 66.2 50 cylindrical cylindrical
Image:D battery size.svg D 20500 1.5 13A LR20 34.2 148 61.5 cylindrical cylindrical

Lantern 26000 6 915A 4R25Y prismatic 885 112 68.2 68.2

Lantern 26000 6 908A 4LR25X prismatic 885 115 68.2 68.2

Lantern 52000 6 918A 4LR25-2 prismatic 1900 127 136.5 73

Discharging performance of all batteries drops at low temperature.[55]

Battery lifetime

Life of primary batteries

Even if never taken out of the original package, disposable (or "primary") batteries can lose 8 to 20 percent of their original charge every year at a temperature of about 20°–30°C.[56] This is known as the "self discharge" rate and is due to non-current-producing "side" chemical reactions, which occur within the cell even if no load is applied to it. The rate of the side reactions is reduced if the batteries are stored at low temperature, although some batteries can be damaged by freezing. High or low temperatures may reduce battery performance. This will affect the initial voltage of the battery. For an AA alkaline battery this initial voltage is approximately normally distributed around 1.6 volts.

Life of rechargeable batteries

Rechargeable batteries traditionally self-discharge more rapidly than disposable alkaline batteries; up to three percent a day (depending on temperature). However, modern Lithium designs have reduced the self-discharge rate to a relatively low level (but still poorer than for primary batteries). Due to their poor shelf life, rechargeable batteries should not be stored and then relied upon to power flashlights or radios in an emergency. For this reason, it is a good idea to keep alkaline batteries on hand. NiCd Batteries are almost always "dead" when purchased, and must be charged before first use.

Although rechargeable batteries may be refreshed by charging, they still suffer degradation through usage. Low-capacity Nickel Metal Hydride (NiMH) batteries (1700-2000 mA·h) can be charged for about 1000 cycles, whereas high capacity NiMH batteries (above 2500 mA·h) can be charged for about 500 cycles.[57] Nickel Cadmium (NiCd) batteries tend to be rated for 1,000 cycles before their internal resistance increases beyond usable values. Normally a fast charge, rather than a slow overnight charge, will result in a shorter battery lifespan.[57] However, if the overnight charger is not "smart" (i.e. it cannot detect when the battery is fully charged), then overcharging is likely, which will damage the battery.[58] Degradation usually occurs because electrolyte migrates away from the electrodes or because active material falls off the electrodes. NiCd batteries suffer the drawback that they should be fully discharged before recharge. Without full discharge, crystals may build up on the electrodes, thus decreasing the active surface area and increasing internal resistance. This decreases battery capacity and causes the dreaded "memory effect". These electrode crystals can also penetrate the electrolyte separator, thereby causing shorts. NiMH, although similar in chemistry, does not suffer from "memory effect" to quite this extent.[59]

Automotive lead-acid rechargeable batteries have a much harder life. Because of vibration, shock, heat, cold, and sulfation of their lead plates, few automotive batteries last beyond six years of regular use. Automotive starting batteries have many thin plates to provide as much current as possible in a reasonably small package. Typically they are only drained a small amount before recharge. Care should be taken to avoid deep discharging a starting battery, since each charge and discharge cycle causes active material to be shed from the plates. Hole formation in the plates leads to less surface area for the current-producing chemical reactions, resulting in less available current when under load. Leaving a lead-acid battery in a deeply discharged state for any significant length of time allows the lead sulfate to crystallize, making it difficult or impossible to remove during the charging process. This can result in a permanent reduction in the available plate surface, and therefore reduced current output and energy capacity.

"Deep-Cycle" lead-acid batteries such as those used in electric golf carts have much thicker plates to aid their longevity. The main benefit of the lead-acid battery is its low cost; the main drawbacks are its large size and weight for a given capacity and voltage. Lead-acid batteries should never be discharged to below 20% of their full capacity, because internal resistance will cause heat and damage when they are recharged. Deep-cycle lead-acid systems often use a low-charge warning light or a low-charge power cut-off switch to prevent the type of damage that will shorten the battery's life.

Special "reserve" batteries intended for long storage in emergency equipment or munitions keep the electrolyte of the battery separate from the plates until the battery is activated, allowing the cells to be filled with the electrolyte. Shelf times for such batteries can be years or decades. However, their construction is more expensive than more common forms.

Extending battery life

Battery life can be extended by storing the batteries at a low temperature, as in a refrigerator or freezer, because the chemical reactions in the batteries are slower. Such storage can extend the life of alkaline batteries by ~5%; while the charge of rechargeable batteries can be extended from a few days up to several months.[60] In order to reach their maximum voltage, batteries must be returned to room temperature; therefore, alkaline battery manufacturers like Duracell do not recommend refrigerating or freezing batteries.[61]

Battery hazards

A battery explosion is caused by the misuse or malfunction of a battery, such as attempting to recharge a primary (non-rechargeable) battery,[62] or short circuiting a battery.[63] With car batteries, explosions are most likely to occur when a short circuit generates very large currents. In addition, car batteries liberate hydrogen when they are overcharged (because of electrolysis of the water in the electrolyte). Normally the amount of overcharging is very small, as is the amount of explosive gas developed, and the gas dissipates quickly. However, when "jumping" a car battery, the high current can cause the rapid release of large volumes of hydrogen, which can be ignited by a nearby spark (for example, when removing the jumper cables).

When a battery is recharged at an excessive rate, an explosive gas mixture of hydrogen and oxygen may be produced faster than it can escape from within the walls of the battery, leading to pressure build-up and the possibility of the battery case bursting. In extreme cases, the battery acid may spray violently from the casing of the battery and cause injury. Overcharging—that is, attempting to charge a battery beyond its electrical capacity—can also lead to a battery explosion, leakage, or irreversible damage to the battery. It may also cause damage to the charger or device in which the overcharged battery is later used. Additionally, disposing of a battery in fire may cause an explosion as steam builds up within the sealed case of the battery.[63]

Environmental concerns

Battery manufacture consumes resources and often involves hazardous chemicals. Used batteries also contribute to electronic waste. Some areas now have battery recycling services available to recover some of the materials from used batteries.[64] Batteries may be harmful or fatal if swallowed.[65] Recycling or proper disposal prevents dangerous elements (such as lead, mercury, and cadmium) found in some types of batteries from entering the environment. In the United States, Americans purchase nearly three billion batteries annually, and about 179,000 tons of those end up in landfills across the country.[66] In the United States the Environmental Protection Agency’s Mercury-Containing and Rechargeable Battery Management Act of 1996, has reduced the amount of mercury in regular household batteries. Recycling programs for lead and cadmium batteries have been put in place.[66] Recycling and disposal regulations may in the future apply to alkaline and nickel-metal hydride batteries.

(Thanks to Wikipedia : By BSa Maxima)